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《Ceramics International》2022,48(9):12660-12674
Zinc oxide is one of the most versatile nanostructured materials with a broad range of applications. Besides, its physicochemical properties can be tuned easily by synthesis conditions to be optimal for a specific application. In our group, we aim for the production of visible light-active materials with enhanced antimicrobial activity. Thus, we synthesize ZnO–Cu2+and Ag@ZnO–Cu2+ by using a fast and robust microwave solvothermal reaction. We investigate the limit of solubility of Cu2+into ZnO lattice producing Cu doped ZnO materials with different doping levels (1, 2, 3, 4, and 5 at. %, Cu/Zn). We also investigate the role of the copper precursor, using copper(II) acetate or copper(II) sulfate as model precursors. Copper acetate incorporates more efficiently into ZnO lattice by decreasing the Eg value of the doped materials at low doping levels. Furthermore, we study the composites Ag@ZnO–Cu2+ aiming to reduce doping levels and to improve antimicrobial activity. Characterization of the materials by different techniques demonstrates their uniform size, purity, crystallinity, and visible light activity. In this study, we evaluate airborne fungal contamination and demonstrate the capacity of ZnO–Cu2+ and Ag@ZnO–Cu2+ to inhibit fungal growth. We studied the microbiological quality of indoor air (vivarium) by sampling air under different conditions. By sampling air with a photocatalytic prototype, the amount of fungi in the air decreases considerably, particularly fungi that can enter the lung. In addition, ZnO–Cu2+ shows excellent antifungal activity against Candida sp at low doses. We use Atomic force microscopy (AFM) and holotomographic microscopy (HTM) to provide further evidence on the capacity of the prepared materials to achieve effective damage to fungal cells and to inhibit biofilm formation. 相似文献
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针对超(超)临界机组参数提高、材质升级,化学技术监督中的监督指标对机组经济性和可靠性影响较大的问题,本文通过机组典型案例分析、技术监督报告、现场实测等,对目前化学监督中影响较大的、关键的技术指标进行了系统性的分析研究。研究结果找出了6项化学监督中超(超)临界机组关键的、影响较大的控制监督指标,且提出了指标控制值和控制方法。这项系统性研究分析方法对指导超(超)临界机组化学监督具有重要的借鉴作用,以控制超(超)临界机组因参数提高和材质升级带来的新问题和新挑战。 相似文献
4.
《工程(英文)》2020,6(12):1423-1431
China’s past economic growth has substantially relied on fossil fuels, causing serious air pollution issues. Decoupling economic growth and pollution has become the focus in developing ecological civilization in China. We have analyzed the three-decade progress of air pollution controls in China, highlighting a strategic transformation from emission control toward air quality management. Emission control of sulfur dioxide (SO2) resolved the deteriorating acid rain issue in China in 2007. Since 2013, control actions on multiple precursors and sectors have targeted the reduction of the concentration of fine particulate matter (PM2.5), marking a transition to an air-quality-oriented strategy. Increasing ozone (O3) pollution further requires O3 and PM2.5 integrated control strategies with an emphasis on their complex photochemical interactions. Fundamental improvement of air quality in China, as a key indicator for the success of ecological civilization construction, demands the deep de-carbonization of China’s energy system as well as more synergistic pathways to address air pollution and global climate change simultaneously. 相似文献
5.
从制冷空调企业的现状出发,利用校企协同、产教融合的创新组织模式,整合暖通行业、企业和学校的资源优势,构建一套“协同创新”的制冷空调课程体系,从根本上提高建环专业学生工程素养和创新能力,以满足暖通行业、企事业单位对具有实践及创新能力的高素质应用型技术人才需求。 相似文献
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Monower Sadique Hassan Al-Nageim Karl Stopps 《International Journal of Pavement Engineering》2019,20(1):100-111
The comparison pairs of cores (each 100 mm apart) from 68 reinstatements sites from various parts of the UK revealed that, the compounding consequences of generic non-homogeneous characteristics of hand laid recipe mixed materials (specified in Specification for the Reinstatement of Openings in Highways (SROH)) and high likeliness of being biased during air void (AV) testing makes the coring method extremely unreliable with very low repeatability and reproducibility. The wide-ranging maximum density reported in every instance in the comparison pair coring experiments meaningfully rationalizes the distorted homogeneity of materials. Although not only maximum density but also bulk density of adjacent cores located only 100 mm apart were found to be varied in the case of every pair in this study. Furthermore, the in situ performance shown by from 50 reinstatements after experiencing 1.5–10 years real-life ageing from various parts of the UK predictably indicates that either the linkage between the reinstatement with non-compliant AV and its impact on footways durability is non-proven or the reported AV content is extremely over estimated. At 95% level of significance, there exists enough evidence to conclude that, due to high uncertainty, very low repeatability and reproducibility and poor reliability with high chances of bias, the assessment of hand laid reinstatement work by AV testing will expose both the contractor and the client to unacceptable risk. 相似文献
8.
Blowdown testing offers a cost-effective experimental tool to replicate the aerothermal conditions in numerous high speed systems. The wind tunnel must replicate the inlet operating conditions, while the spatial and time dependent inlet flow conditions should be assessed carefully. This paper provides a design methodology and rules that ensure adequate flow conditioning in high inlet pressure wind tunnels suitable for subsonic and supersonic operation with mass-flow limits ranging from 1 kg/s to 25 kg/s, Reynolds numbers from 103 (1/m) to 4x107 (1/m), and Mach numbers from 0.01 up to 6. The quality of the proposed flow conditioning system was evaluated using stereo PIV measurements combined with hotwire, Pitot probe, and total flow temperature traverses. 相似文献
9.
《International Journal of Hydrogen Energy》2021,46(68):33934-33947
High temperature PEM fuel cells show enhanced tolerances regarding fuel impurities like CO for use in various applications. However, the impact of air impurities like NOx on the cell behavior is not completely understood yet. This study provides systematic investigation during 500 h of operation in presence of cathode air containing 10 ppm NO or NO2. Nitrogen oxides provoke a strongly and linearly decreasing voltage of 245.3 ± 18.5 μV h−1 and highly comparable damage that verifies similar HT-PEMFC degradation via both oxides. Cyclic voltammetry and electron microscopy reveal the loss of electrochemical catalyst surface by selectively poisoned surface and enforced catalyst particle growth. Impedance spectroscopy reveals besides increased electrode charge transfer resistances an affected proton conductivity. In contrast, SO2/NO2 impurity mixture in real occurring ratio causes less voltage decay due to a positive SO2 impact through H2SO4 formation causing further shown and discussed effects like nitrate formation and discharge. 相似文献
10.
Air blast, a sudden mass movement of air, can occur in underground mining system where caving develops an extensive mass of unsupported rock spanning a large void. Air blast can result in injury to mine personnel, damage to equipment or disrupts mine operation. Evaluation of air blast parameters is, therefore, an essential part to develop strategies to mitigate the hazard. The properties of a muckpile or a caved zone are significant factors affecting the magnitude of air blast in particular on the undercut and extraction levels. This research investigates the effect of muckpile properties on air flow using the numerical code, PFC2D. The critical parameters such as thickness, block size and porosity (swell factor) of the muckpile have been studied to quantify how much they could change the magnitude of air pressures and velocities while the air flows through the muckpile. It was found that the porosity of the muckpile is the most effective parameter on the magnitude of air blast and by designing a thick layer of blasted rock with low porosity in the caved zone, the intensity of the air blast can be significantly reduced. The findings of this study can be used to design air blast plugs or bulkheads in order to isolate any potential air blast from the active workings, or to quantify the minimum thickness of the muckpile above extraction levels to manage air blast hazards. 相似文献